tert-Butyl peroxyacetate (TBPA)

tert-Butyl peroxyacetate (TBPA)
tert-Butyl peroxyacetate (TBPA)
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CAS No.: 107-71-1
  • Chemical Family Organic Peroxide
  • Molecular Formula C₆H₁₂O₃
  • Molecular Weight 132.18
  • UN No. 3103
  • Transport Hazard Class 5.2
  • Available in 70% and 50% solutions

Half-Life Period

  • 0.1 hour 139℃
  • 1 hour 119℃
  • 10 hours 100℃
  • Appearance: clear, colorless liquid that can be diluted using solvents such as benzene, odorless mineral oil, or isododecane
  • Solubility: Insoluble in water, soluble in most organic solvents
  • Decomposition temperature: 159℃
  • Density: 0.923 (20℃)
  • Refractive index: 0.1035 (20℃)
  • Purity: 70% min, 50% min
  • Available oxygen: 8.96% min, 5.93% min
  • Free acid: 0.5% max
  • Theoretical active oxygen content: 12.11%
  • Major decomposition products: tert-butyl alcohol, acetic acid, di-tert-butyl ether, methane, ethane
  • Activation energy E(KJ/mol) : 149.36
  • Self-accelerating decomposition temperature (SADT): 70℃
  • Hazardous temperature (Tem): 65℃
  • Storage temperature (Ts min/Ts max): -15/10℃
Applications
  • Excellent low-temperature initiator for high-pressure polyethylene (LDPE) production, especially suited for tubular reactor processes. When used together with other initiators like LQ-TBPV (tert-butyl peroxyvalerate), LQ-TBPEH (tert-butyl peroxy-2-ethylhexanoate), and LQ-TBPB (tert-butyl peroxybenzoate), it enhances the overall polymerization process, improving efficiency and end-product quality.
  • An excellent option for high-temperature curing in unsaturated polyester applications, ensuring efficient crosslinking and reliable end results.
  • From styrene to vinyl acetate and methacrylates, TBPA facilitates a wide range of polymerization reactions, ensuring fast processing times and improved polymer properties.
  • Packaging

    Supplied in standard 20 kg polyethylene drums, with options for customized packaging sizes to fit specific needs.

  • Validity

    Stored under the recommended conditions, tert-Butyl peroxyacetate (TBPA) retains its quality for up to three months.

  • Safe Handling

    Store in a cool, well-ventilated area, keeping the temperature below 30°C.
    Ensure the product is kept away from any heat sources or open flames, and store separately from acids, reducing agents, and flammable materials.
    The storage area should have explosion-proof lighting and ventilation, with electrical switches located outside the area.
    Handle carefully to avoid damaging the packaging or containers. Avoid any impacts or vibrations during handling, and always use personal protective equipment.
    Please refer to the Safety Data Sheet (MSDS) for detailed handling and storage instructions.

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